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Diesel Fuel’s Dirty Little Secret Revealed

    Not too many things in life are a sure bet except for death and taxes as the saying goes, but maybe we can add one more to the list. It would be this one fact: diesel fuel is inherently unstable. That’s right, and with each transfer from one storage outlet to another in the supply chain, the fuel can become contaminated.  Diesel fuel is subject to water incursion, microbial and bacterial growth and particulate contamination. So what exactly does that mean? Well, if you are storing diesel for any purpose like an emergency back up generator, an above or below ground storage tank or diesel that goes unused for prolonged periods of time in power equipment or marine vessels then you have problems waiting to happen. 

 

    Like what?  Maybe a little diesel fuel history and chemistry are in order to put things into perspective.

 

    In an effort to reduce diesel fuel emissions, The United States adopted new emissions standards for “Low Sulfur Fuel” for all on-highway applications in 1994 as determined by a standard from ASTM, the organization that establishes these standards.  This new diesel fuel standard for sulfur content was reduced from the previous 0.5% to 0.05%, or not more than 500 parts per million.  Fast forward to 2006.  ULSD (Ultra Low Sulfur Diesel) became widely available in the United States. Because of stricter clean air standards and engine manufacturer’s requirements, a full transition to ULSD with a maximum sulfur level that is currently only 15 parts per million applies to 100% of on-highway and off-road diesel fuel.

 

    Sounds great, right? Well, yes and no.  This is good news for Mother Nature.  Less sulfur in the air means less pollution and a cleaner and healthier planet for all of us.  Unfortunately, not such good news for diesel engines because in the process of removing the sulfur, much of the lubricity fuel systems require was removed. Diesel engines were designed to run on oil (fuel oil #2), which has as inherent slipperiness referred to as lubricity.  This lubricity is required for the injection pump and injectors themselves. Why is lubricity important?  Because without lubricity the engine is compromised causing premature equipment failure from high wear or scarring between contacting metal parts resulting in possible catastrophic failure. Definitely not good.

 

    So, in order to correct this problem, biodiesel is now added during the refining process, which provides this essential lubricity. But… biodiesel creates its own set of problems, like water.  Water is arguably diesel fuels’ worst enemy and can be in the form of free, dissolved or emulsified states. Biodiesel reduces the molecular surface tension where water and diesel fuel meet allowing for water present in fuel to more readily disperse throughout the fuel thereby becoming entrained into the fuel.  This will appear as hazy fuel.

 

    Water also enters fuel tanks through ill-fitting, missing or corroded caps and openings or vents in the tank’s top. Humid air entering through vents and daily temperature fluctuations cause water droplets to condensate on the inside tank walls even with a "full" tank. There is always a 10% or more headspace that allows for fuel expansion/contraction. Water droplets form on the tank walls in this space and settle on the tank bottom. The more interior tank wall exposure, the more potential for water accumulation.

 

    Water in its free state settles on the tank bottom where acids form causing corrosive damage to the sides and bottom potentially causing bottom structure failure and/or leaking.  Water is also the number one culprit for creating the perfect environment for microbial growth, often called diesel bug or “algae.” These microbes can grow with less than 0.25 inches of water present in the tank bottom.  These toxic bacteria, mold and fungus feed off of the fuel hydrocarbons and reproduce exponentially forming additional waste products and acids at the bottom of the tank. They can also coat the walls and baffles of the fuel tank, clogging fuel filters, producing dark smoke exhaust and damaging engine components such as injectors and fuel pumps. Biocides are the common remedy if microbial growth is present but use of these can actually aggravate the situation and turn bio-film into solids which is a filter plugging nightmare!  Biocides have limited effectiveness.  They do not kill all microbial growth so the unaffected bugs will continue to reproduce establishing a continuous cycle of only short-term relief with their use.  The bottom line is that no matter how vigilant the steps taken are, water contamination in fuel tanks is a fuel systems’ number one enemy that can lead to a cascade of costly and potentially catastrophic events. If there is no water present in the fuel there is nowhere for microbes to live, survive and thrive. Period.

 

    Other contaminants from the natural degradation of diesel fuel wreak havoc on the entire fuel system as well.  Wax-waxes in diesel can solidify if temperatures fall below a certain point and cause filter blockage.  Dirt and Particulates-inorganic substances like dirt, sand, rust and dust cause damage to the fuel systems injectors and other components resulting in increased engine wear, abrasion and potential engine failure.

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    Solids-asphaltenes are naturally occurring and are not soluble in fuel and tend to cluster forming solids or sludge that settle in the tank bottom.  This sludge is composed of asphaltenes as well as microbes,  organic/inorganic waste compounds and other contaminants.

     And now a word about additives.  There are many different additives available in the market today i.e. lubricity enhancers, cetane boosters, cold flow improvers, biocides, corrosion inhibitors, anti-oxidants and fuel stabilizers to name a few. Fuel refiners incorporate additives into the manufacturing process.  Lubricity additives are typically added at the product distribution terminal.

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     Additive impact and compatibility need to be understood and respected.  Additives are like medicine for your fuel and expert prescribing is necessary.  Indiscriminate use can cause more harm than good because of unexpected interactions. 

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     It should be noted that some fuel additives are more reactive than others like lubricity improvers or certain corrosion inhibitors that can react with water and form soaps.  These soaps can diminish additive effectiveness

and become inert and capable of plugging filters and causing injection system problems.

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    Many additives can form surfactants that facilitate the emulsification of fuel which appears cloudy above the fuel/water interface. This water is extremely difficult to then remove. Since we are aware that the single most destructive substance in fuel is water, we want to avoid this scenario. 

 

    It should be abundantly clear that efforts to get water out and keep water out are far more productive than spending time and money adding unnecessary and complex additives to create a science project in your tank that promotes keeping the water bound to the fuel molecule.  Removing the water habitat from the microbes is far more cost effective than spending money on biocides that are ineffective days after treatment because the microbes will return after the biocide wears off.  Additionally, the sludge that forms from dead microbes is greater from using a regularly scheduled biocide kill strategy than getting the water out and keeping the water out strategy. 

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     The petroleum industry recommends checking tanks weekly for water and draining any accumulated water every two weeks through the gravity drain located at the low point of the tank. Unfortunately, the construction and design of flat bottom storage tanks DOES NOT allow for a bottom drain. This flat design was created to mount the generator above the tank for convenience and to save space with no water draining option.


   

  What to do now?


    Call Spin Clean Technologies!   The only way to remove the water and sludge from a sub base fuel tank with no drainage system is by vacuuming the water out from the bottom through the tank top fill or vent openings on a regular basis. Filtering the fuel from the bottom of the tank and recirculating it back into the tank is not an ideal process. This method, used by most fuel cleaning companies, of chopping and breaking the water molecules during the cleaning process and mixing the water/sludge layer with the fuel above it, makes separation difficult, if not impossible. SpinClean uses a non-electric, air driven diaphragm pump that gently moves the fuel through the pump, with no grinding or mixing, allowing for maximum water/sludge separation.

     

     The SpinDri process was intentionally designed to remove the water and sludge from the tank bottom to a separate tank through an extraction process rather than merely filtering the fuel which recirculates the water/sludge into the top fuel layer, as mentioned above. 

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     SpinDri also includes a powerful rinse cycle where ultra clean fuel is used under high pressure to loosen and remove water and sludge around the interior tank baffles. 

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    Call SpinClean today for a FREE fuel analysis and consultation.

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